Cuprophilicity
WebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported Cu I –Cu I interaction in two recently reported complexes Josep-M. Poblet and M. Bénard, … WebJan 7, 2005 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract.
Cuprophilicity
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WebNov 17, 2000 · DFT calculations suggest the ligand‐unsupported cuprophilicity orginate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal/mol. View. Show abstract. WebMay 22, 2024 · Cuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.-C. Chen, Y.-C. Tsai, and co-workers report in their Communication on page 9925 ff. the synthesis and characterization of two dodecacopper(I) chain-like complexes via intermolecular Cu–Cu coupling of two linear hexacopper monomers. Their …
WebDec 29, 2004 · To verify whether attractive metallophilic interactions exist in the dimer-of-dimers [Cu 2 (ophen) 2] 2 (Hophen=1H-[1,10]phenanthrolin-2-one) (1), we designed and synthesized a series of such [M 2 L 2] 2 structures by varying the d 10 metal and/or the ligand (M=Cu I or Ag I, L=ophen or obpy; Hobpy=1H-[2,2′]bipyridinyl-6-one), and have … WebCuprophilicity? a rare example of a ligand-unsupported CuI–CuI interaction - Chemical Communications (RSC Publishing) SCHEDULED MAINTENANCE Maintenance work is …
WebTheoretical calculations break down the attractive and repulsive forces associated with cuprophilicity, its spontaneous 4p–3d hybridization origin, and direction-dependent … WebCuprophilicity is still under debate, while aurophilicity and argentophilicity are well recognized. I.‐C. Chen, Y.‐C. Tsai, and co‐workers report in their Communication (DOI: 10.1002/anie ...
Web3⋯I) interactions, cuprophilicity, and Fig. 1 Crystal structure of the adduct with intermolecular Cu 3⋯I (π-acid⋯base) and Cu⋯Cu interactions (a) and N⋯H hydrogen bonds (b)
WebThe organic ligand 4-dpda is chosen to amplify the perturbation toward metallophilic interations for steric hindrance, and many of the molecular interactions of its multi- … some easy to drawWeb[Cu (SCN)] (1), which can also be viewed as a 3-D network constructed by linkages of 2-D sheets and 1-D chains via unsupported CuI-CuI interactions. The CuI-CuI contact of 2.651 (4) A in 1 is the... small business mentorship initiativeWebJan 10, 2024 · Theoretical calculations break down the attractive and repulsive forces associated with cuprophilicity, its spontaneous 4p-3d hybridization origin, and direction … someecards out of officeWebJul 26, 2024 · Compared with their THF-bound hexacopper(I) monomers and protonated ligands, these ligand-unsupported cuprophilic interactions are shown to be weak by Raman spectroscopy. DFT calculations suggest the ligand-unsupported cuprophilicity originate from weak attractive orbital interactions, and the strength is estimated to be 2.4 kcal mol-1 . small business mentorsWebCuprophilicity, a still elusive concept: a theoretical analysis of the ligand-unsupported CuI–CuI interaction in two recently reported complexes - Chemical Communications (RSC Publishing) Jump to main content Jump to site search Publishing Journals Books Databases Advanced Log in / register Issue 11, 1998 Previous Article Next Article some easy sketchesWebApr 28, 2024 · Abstract. Synthesis and characterization of two dodecacopper (I) extended metal atom chains (EMAC) assembled by two hexadentate bis (pyridylamido)amidinate … someecards office birthdayWebMar 25, 2024 · The concept of accomplice liability means an accomplice faces the same degree of guilt and punishment as the individual who committed the crime. Indeed, … small business merchandising